Make an energy balance and distinguish energy conservation from useful work.
2 core ideas1 source trails3 recall prompts
Energy boundary01—04
Account for every transferHeat and work cross a boundary; internal energy records the stored change.Energy · Modules
Build the idea
An original introduction, worked example and practice, followed by a curated reading sequence. The external courses supply deeper teaching and problem sets.
Scope and safety
This guide is an orientation, not a complete university module. Practical work needs suitable facilities, safety review and supervision.
Thermodynamics accounts for energy and constrains what energy conversions are possible. Start by drawing the system boundary and declaring a sign convention.
Module lens
Make energy cross a boundary
Heat and work are transfers; internal energy records what remains stored in the selected system.
Core relationshipΔU = Q − W
Track
J · heat · work · state
Ask yourself
Can ΔU fall while Q enters?
Original Lilerno schematic · conceptual, not to scale
01
Distinguish property and transfer
Internal energy is a state property. Heat and work describe transfer across a boundary, not substances stored inside the system. For a closed system with negligible kinetic and potential energy change, ΔU = Q − W when work out is positive.
02
Conservation is not efficiency
The first law conserves energy. The second law constrains direction and useful work: entropy generation is nonnegative. A heat engine's efficiency uses net work output divided by heat input, not total energy passing through every component.
Energy boundary01—04
Account for every transferHeat and work cross a boundary; internal energy records the stored change.
See the relationship
Change one quantity, watch the graph respond, then explain the result in your own words.
Predict → change → explain
Account for energy crossing a boundary
Can internal energy fall even while heat enters?
1Heat Q enters
2Closed system
3Work W leaves
4ΔU = Q − W
Heat in
800 J
Work out
300 J
ΔU
500 J
Closed-system boundary. Heat enters and work leaves; ΔU is a change in stored energy, not another transfer.
ΔU = Q − W
Chosen balance
Axes: Work out (J) → Internal energy change (J). Bounds may rescale when inputs change.
800 J in − 300 J out = 500 J stored change. Negative ΔU means internal energy decreases.
Model assumptions and limits
Closed system; heat into the system and work out are positive. Changes in kinetic and potential energy are neglected.
Original Lilerno illustration. Inputs are illustrative; this is not experimental evidence or a design rating.
Inspect the plotted values
Work out (J) and Internal energy change (J); values rounded to four significant figures.
Series
Work out (J)
Internal energy change (J)
ΔU = Q − W
0
800
ΔU = Q − W
18.75
781.3
ΔU = Q − W
37.5
762.5
ΔU = Q − W
56.25
743.8
ΔU = Q − W
75
725
ΔU = Q − W
93.75
706.3
ΔU = Q − W
112.5
687.5
ΔU = Q − W
131.3
668.8
ΔU = Q − W
150
650
ΔU = Q − W
168.8
631.3
ΔU = Q − W
187.5
612.5
ΔU = Q − W
206.3
593.8
ΔU = Q − W
225
575
ΔU = Q − W
243.8
556.3
ΔU = Q − W
262.5
537.5
ΔU = Q − W
281.3
518.8
ΔU = Q − W
300
500
ΔU = Q − W
318.8
481.3
ΔU = Q − W
337.5
462.5
ΔU = Q − W
356.3
443.8
ΔU = Q − W
375
425
ΔU = Q − W
393.8
406.3
ΔU = Q − W
412.5
387.5
ΔU = Q − W
431.3
368.8
ΔU = Q − W
450
350
ΔU = Q − W
468.8
331.3
ΔU = Q − W
487.5
312.5
ΔU = Q − W
506.3
293.8
ΔU = Q − W
525
275
ΔU = Q − W
543.8
256.3
ΔU = Q − W
562.5
237.5
ΔU = Q − W
581.3
218.8
ΔU = Q − W
600
200
ΔU = Q − W
618.8
181.3
ΔU = Q − W
637.5
162.5
ΔU = Q − W
656.3
143.8
ΔU = Q − W
675
125
ΔU = Q − W
693.8
106.3
ΔU = Q − W
712.5
87.5
ΔU = Q − W
731.3
68.75
ΔU = Q − W
750
50
ΔU = Q − W
768.8
31.25
ΔU = Q − W
787.5
12.5
ΔU = Q − W
806.3
-6.25
ΔU = Q − W
825
-25
ΔU = Q − W
843.8
-43.75
ΔU = Q − W
862.5
-62.5
ΔU = Q − W
881.3
-81.25
ΔU = Q − W
900
-100
ΔU = Q − W
918.8
-118.8
ΔU = Q − W
937.5
-137.5
ΔU = Q − W
956.3
-156.3
ΔU = Q − W
975
-175
ΔU = Q − W
993.8
-193.8
ΔU = Q − W
1013
-212.5
ΔU = Q − W
1031
-231.3
ΔU = Q − W
1050
-250
ΔU = Q − W
1069
-268.8
ΔU = Q − W
1088
-287.5
ΔU = Q − W
1106
-306.3
ΔU = Q − W
1125
-325
ΔU = Q − W
1144
-343.8
ΔU = Q − W
1163
-362.5
ΔU = Q − W
1181
-381.3
ΔU = Q − W
1200
-400
ΔU = Q − W
1219
-418.8
ΔU = Q − W
1238
-437.5
ΔU = Q − W
1256
-456.3
ΔU = Q − W
1275
-475
ΔU = Q − W
1294
-493.8
ΔU = Q − W
1313
-512.5
ΔU = Q − W
1331
-531.3
ΔU = Q − W
1350
-550
ΔU = Q − W
1369
-568.8
ΔU = Q − W
1388
-587.5
ΔU = Q − W
1406
-606.3
ΔU = Q − W
1425
-625
ΔU = Q − W
1444
-643.8
ΔU = Q − W
1463
-662.5
ΔU = Q − W
1481
-681.3
ΔU = Q − W
1500
-700
Chosen balance
300
500
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Original Lilerno example
A closed system receives 500 J of heat and performs 200 J of work; kinetic and potential changes are negligible.
01
Declare Q positive into the system and W positive out.
02
Apply ΔU = Q − W.
03
ΔU = 500 − 200 = 300 J.
ΔU=Q−W=300J
Mass crossing the boundary would require an open-system balance with flow terms.
Energy boundary01—04
Account for every transferHeat and work cross a boundary; internal energy records the stored change.
Test the model
Open learning, traceable sources
Work in this order. These links open the publisher’s material; free access does not always permit republication.
Start with: Fundamentals → second law → power cycles
Work through lecture notes, recitations and assignments. Draw a boundary for every balance.
Recall, then record
Close the explanation and answer these in your own words. Return tomorrow, then again later in the week.
01
Is mass crossing the boundary?
02
Which work sign convention?
03
What does the second law add?
Engineering notebook
Draw an energy-flow diagram for an everyday device. Separate measured inputs from assumptions; do not open or modify the device.
Your study record
Self-reported tasks, not an assessment of mastery or university credit. Reading a page does not complete a chapter.
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Open learning, traceable sources
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Checked 2026-09-06
Original Lilerno lessons and diagrams, supported by these references. Free access does not always permit republication. Links open the publisher’s material.
16.050 · Thermal Energy (2002)MIT OpenCourseWare+
Thermodynamic foundations, second law, power cycles and heat transfer. Aerospace examples share the mechanical-engineering energy principles.
CC BY-NC-SA 4.0 except separately credited material. Linked for external study, not reproduced. Some assigned textbooks/software require separate access.